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How wet is wet?

An answer with liquid Helium

wet

When we talk about wet granular matter, an obvious question is: At which liquid content (e.g. volume ratio between liquid and particle) do you need to consider the influence of wetting? The answer with liquid helium as wetting liquid (perfect wetting, well controlled liquid volume) is: A few atomic layers of liquid layer thickness on average is sufficient. That means, wetting starts to influence the rigidity of granular materials even if there is only unsaturated liquid film covering the asperities of particles.

helium setup

Sketch of the helium wetting setup. Some pictures of the setup can be found here.



Using the critical acceleration to fluidize the granular layer as the order parameter, we quantify how the amount of wetting liquid added changes the rigidity of the material.

Dry granular media fluidizes at a driving acceleration of around 1.2g with g graviational acceleration, while for wet granular media the critical acceleration for fluidization will increase monotonically with the amount of wetting liquid added until a plateau regime is reached. The difference between critical acceleration for dry and wet granular media represents the influence from capillary forces. This experiment is to explore the wetting of granular media by liquid helium, which wets almost all the substrate and have a phase transition from normal fluid (helium I) to superfluid (helium II) while it is cooled below the 'lambda' point (2.17K for bulk helium).

lh_critical acceleration

For wetting by helium I, the critical acceleration for fluidization shows a steep increase close to the saturation of the vapor pressure in the sample cell. While for helium II wetting, the critical acceleration starts to increase at about 75% saturation (see the red dash line), indicating that capillary bridges are enhanced by the superflow of unsaturated helium film.

The enhancement by superfluid could be understood in the following way: suppose two particles start to fluidize and collide with each other, there will appear a slightly heat up spot at the colliding point, which facilitates the fountain effect so that superfluid part of the helium film tends to flow to this point and enhance the capillary bridges between the two particles.



Reference

 



Universität Bayreuth - last updated at 25.10.2016 by Kai Huang